中国稻田甲烷产生和排放研究 Ⅱ.模式研究和减排措施     

任万辉  许黎  王振会  M.A.K.Khalil  R.A.Rasmussen 《气象》2004,30(7):3-7

主要介绍了近 2 0年来稻田甲烷排放的模式研究和排放量的估算以及减少稻田甲烷排放的措施。数值模式是估算稻田甲烷排放量的一条有效途径 ,模式的研究现在正处于发展阶段。介绍了几个主要的模型 ,既有物理过程模型也有经验模型。年排放量的估算范围为 6 79～ 4 1 4Tg ,随着技术的发展和大量实验的进行估算值的精度正得到不断的提高。减排措施是减少稻田甲烷排放的必要手段 ,但是目前的减排技术均处于研究阶段 ,应用还不成熟  相似文献   

煤层气在煤储层中的扩散及其影响因素   总被引：4，自引：0，他引：4  

曹成润  牛伟  张遂安  霍永忠  陈秀艳  孙英男 《世界地质》2004,23(3):266-269

煤层气在煤储层中的扩散是指从煤基质孔隙表面上解吸的煤层气运移到割理系统的主要过程。发生扩散的前提条件是气体浓度差的出现，衡量扩散能力大小的重要参数是扩散系数。前者为由解吸速度、解吸气量和煤层气产量、井孔压力降等因素控制的动态参数，而后者为主要受扩散物质性质、扩散介质特征、扩散系统的温度、压力和孔隙结构形态等因素影响的静态参数。煤层气在煤储层中的扩散量与煤层气浓度差和扩散系数呈正比关系。  相似文献   

Kinetic-simulating experiment combined with GC-IRMS analysis: application to identification and assessment of coal-derived methane from Zhongba Gas Field (Sichuan Basin, China)   总被引：2，自引：0，他引：2  

Yongqiang Xiong  Ansong Geng  Jingzhong Liu 《Chemical Geology》2004,213(4):325-338

The main purpose of this study is to model the δ¹³C values of methane derived from coal by combining kinetic-simulating experiment with the gas chromatography-isotope ratio mass spectrum (GC-IRMS) analysis. The stable carbon isotopic variation of methane in pyrolysates with heating temperature indicates that the assumptions for both a constant kinetic isotope effect (α) and a uniform initial isotopic composition (δ¹³C_o) are impractical for explaining the carbon isotopic fractionation during coalification. For purposes of simplification, two approaches are used in this paper to deal with the heterogeneity of terrestrial organic matter. One is that, assuming a uniform initial isotopic composition (i.e., δ¹³C_{i, o}=δ¹³C_o) for all methane-generating precursors in coal, the isotopic variation of methane is fitted by adjusting ΔE_{a, i} (E_{a¹³C, i}−E_{a¹²C, i}) for each hypothetical reaction. The other is that, assuming a constant kinetic isotope effect during the whole gas formation, that is all ΔE_{a, i} values are identical, the modeling of methane isotopic composition is achieved by changing the ¹³CH₄ generation potential of each reaction (f_{i, ¹³C}), namely, by adjusting the initial δ¹³C value (δ¹³C_{i, o}) for each methane-generating precursor. Results of the kinetic calculation shows that the two simulating methods can yield a similar result at a geological heating rate of 2 °C/My, which further demonstrates that those natural gases with methane δ¹³C value being approximately −36‰ are possibly sourced from the upper Triassic coal measure strata in the Northwestern Sichuan Basin.  相似文献   

Application of AVO Analysis to Seismic Data for Detection of Gas below Methane Hydrate Stability Zone in Nankai Trough Area     

Masami Hato    Takao Inamori    Alfian Bahar  Toshifumi Matsuoka 《Resource Geology》2004,54(1):105-113

Abstract. For the purpose of development of methane hydrate, occurring in the deep marine subsurface, as a resource, the most important issue is to understand the methane hydrate system (generation, migration and accumulation) as well as to delineate the methane hydrate reservoir properties. We have applied the Amplitude Versus Offset (AVO) analysis to the seismic data acquired in the Nankai Trough, offshore Japan, in order to confirm the occurrence of gas just below the methane hydrate-bearing zone, assuming that gas will show a so-called Class-3 AVO response. Knowledge of the amount and occurrence of gas in the sediment below methane hydrate-bearing zone is one of the keys to understand the methane hydrate system.
We have utilized the qualitative analysis of AVO methodology to delineate how gas is located below the BSR, which is thought to be the reflection event from the interface between the methane hydrate-bearing zone and the underlying gas-bearing zone. In the region of MITI Nankai Trough Well PSW-3, we observe two BSRs separated by 25 ms. After AVO modeling using well data, we applied AVO attribute analysis and attribute crossplot analysis to the seismic data. Finally we applied an offset-amplitude analysis to CMP gather data at specific locations to confirm the results of AVO attribute analysis. The AVO analysis shows that there is very little gas located in the underlying sediment below methane hydrate-bearing zone. This result supports the fact that we could not obtain any clear evidence of gas occurrence just below the methane hydrate-bearing zone in the Nankai Trough well drilling.  相似文献   

Detection of Methane Hydrate-Bearing Zones from Seismic Data     

Takao Inamori  Masami Hato 《Resource Geology》2004,54(1):99-104

Abstract. The MITI Nankai Trough wells were drilled offshore Japan in the Tokai area in 1999 and 2000. The occurrence of methane hydrate was confirmed by various indicators in the borehole logs and from core data. These findings have a large impact on potential future Japanese energy resources and other related-scientific interests.
We first tried to find the methane hydrate-bearing zones using interval velocities derived from NMO velocity analysis. However, this analysis produced poor resolution. To achieve a more detailed delineation of the gas hydrate- and gas-bearing zones, we executed a seismic impedance inversion calibrated by the logs from two of the MITI Nankai Trough wells. Although these two wells are only about 90 m apart, we were able to produce an impedance section with fine detail by adopting a simple initial model and incorporating physical properties of the methane hydrate-bearing zones. The locations of the methane hydrate-bearing zones are readily apparent in the final section.  相似文献   

Subsurface Occurrence of Natural Gas Hydrate in the Nankai Trough Area: Implication for Gas Hydrate Concentration   总被引：2，自引：0，他引：2  

Takashi Uchida    Hailong Lu  Hitoshi Tomaru 《Resource Geology》2004,54(1):35-44

Abstract. The Nankai Trough runs along the Japanese Islands, where extensive BSRs have been recognized in its forearc basins. High resolution seismic surveys and site-survey wells undertaken by the MITI have revealed the gas hydrate distribution at a depth of about 290 mbsf. The MITI Nankai Trough wells were drilled in late 1999 and early 2000. The highlights were successful retrievals of abundant gas hydrate-bearing cores in a variety of sediments from the main hole and the post survey well-2, keeping the cored gas hydrate stable, and the obtaining of continuous well log data in the gas hydrate-dominant intervals from the main hole, the post survey well-1 and the post survey well-3. Gas-hydrate dominant layers were identified at the depth interval from 205 to 268 mbsf. Pore-space hydrate, very small in size, was recognized mostly filling intergranular pores of sandy sediments. Anomalous chloride contents in extracted pore water, core temperature depression, core observations as well as visible gas hydrates confirmed the presence of pore-space hydrates within moderate to thick sand layers. Gas hydrate-bearing sandy strata typically were 10 cm to a meter thick with porosities of about 40 %. Gas hydrate saturations in most hydrate-dominant layers were quite high, up to 90 % pore saturation.
All the gas hydrate-bearing cores were subjected to X-ray CT imagery measurements for observation of undisturbed sedimentary textures and gas-hydrate occurrences before being subjected to other analyses, such as (1) petrophysical properties, (2) biostratigraphy, (3) geochemistry, (4) microbiology and (5) gas hydrate characteristics.  相似文献   

Flooding of the continental shelves as a contributor to deglacial CH4 rise     

Andy Ridgwell  Mark Maslin  Jed O. Kaplan 《第四纪科学杂志》2012,27(8):800-806

The transition from the last glacial and beginning of Bølling–Allerød and Pre‐Boreal periods in particular is marked by rapid increases in atmospheric methane (CH₄) concentrations. The CH₄ concentrations reached during these intervals, ～650–750 ppb, is twice that at the last glacial maximum and is not exceeded until the onset of industrialization at the end of the Holocene. Periods of rapid sea‐level rise as the Last Glacial Maximum ice sheets retreated and associated with ‘melt‐water pulses’ appear to coincide with the onset of elevated concentrations of CH₄, suggestive of a potential causative link. Here we identify and outline a mechanism involving the flooding of the continental shelves that were exposed and vegetated during the glacial sea‐level low stand and that can help account for some of these observations. Specifically, we hypothesize that waterlogging (and later, flooding) of large tracts of forest and savanna in the Tropics and Subtropics during the deglacial transition and early Holocene would have resulted in rapid anaerobic decomposition of standing biomass and emission of methane to the atmosphere. This novel mechanism, akin to the consequences of filling new hydroelectric reservoirs, provides a mechanistic explanation for the apparent synchronicity between rate of sea‐level rise and occurrence of elevated concentrations of ice core CH₄. However, shelf flooding and the creation of transient wetlands are unlikely to explain more than ～60 ppb of the increase in atmospheric CH₄ during the deglacial transition, requiring additional mechanisms to explain the bulk of the glacial to interglacial increase. Similarly, this mechanism has the potential also to play some role in the rapid changes in atmospheric methane associated with the Dansgaard–Oeschger cycles. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

The Relationship between Jurassic Coal Measures and Sandstone-type Uranium Deposits in the Northeastern Ordos Basin, China     

JIAO Yangquan  WU Liqun  RONG Hui  PENG Yunbiao  MIAO Aisheng  WANG Xiaoming 《《地质学报》英文版》2016,90(6):2117-2132

Outcrop and drill hole data show that the Jurassic coal measures in the northeastern Ordos Basin are composed mainly of the Yan'an Formation and the lowstand system tract of the Zhiluo Formation,and there is a regional unconformity between them. The Dongsheng uranium deposit is associated with the Jurassic coal measures. Research data indicate that the Jurassic coal measures in the study area have a certain hydrocarbon-generating capacity,although the metamorphic grade is low(Ro=0.40%–0.58%). In the Dongsheng region alone,the accumulative amount of generated coalbed methane(CBM) is about 2028.29 × 108 –2218.72 × 108 m~3; the residual amount is about 50.92 × 108 m~3,and the lost amount is about 1977 × 108 m~3. Analysis of the burial history of the host rocks and the evolutionary history of the Dongsheng uranium deposit suggests that the Jurassic coal measures generated hydrocarbon mainly from Middle Jurassic to Early Crataceous,which is the main mineralization phase of the Dongsheng uranium deposit. By the Late Cretaceous,a mass of CBM dissipated due to the strong tectonic uplift,and the Dongsheng uranium deposit stepped into the preservation phase. Therefore,the low-mature hydrocarbon-containing fluid in the Jurassic coal measures not only served as a reducing agent for the formation of sandstone-type uranium deposits,but also rendered the second reduction of paleo-interlayer oxidation zone and become the primary reducing agent for ore conservation. Regional strata correlation reveals that the sandstone-type uranium reservoir at the bottom of the Zhiluo Formation is in contact with the underlying industrial coal seams in the Yan'an Formation through incision or in the form of an unconformity surface. In the Dongsheng region with poorly developed fault systems,the unconformity surface and scour surface served as the main migration pathways for low-mature hydrocarbon-containing fluid migrating to the uranium reservoir.  相似文献   

白杨河矿区煤层气丛式井钻井难点及对策研究          下载免费PDF全文

毛志新  谢相军  汤建江 《探矿工程》2016,43(12):37-40

新疆阜康市白杨河矿区煤层气开发利用先导性示范工程是新疆第一个煤层气示范工程项目。白杨河矿区总体构造为向南倾斜的单斜构造,地层倾角大,煤层多且间距大。该示范工程开发方案主要井型为丛式井。经过多年钻井实践,丛式井钻井技术在鄂尔多斯盆地东缘煤层气区块已经非常成熟,初步形成了一套适合该地区煤层气开发的丛式井钻井技术。由于白杨河矿区地质条件与鄂尔多斯盆地东缘各区块相比差异大,特别是存在地层倾角大、煤层多且间距大等地质特点,因此不能完全照搬原有的丛式井钻井技术。本文依据白杨河矿区地质资料,分析了白杨河矿区煤层气丛式井钻井难点,对解决该区块钻井难点的技术对策和攻关思路进行了总结与阐述,初步形成了一套适合白杨河矿区大倾角厚煤层的丛式井钻井技术。  相似文献   

Numerical modeling study of mineralization induced by methane cold seep at the sea bottom     

《Marine and Petroleum Geology》2016

In order to investigate the response of authigenic minerals to gas hydrate geo-systems, the biogeochemical processes and its induced mineralization were predicted by employing the comprehensive reactive transport modeling approach. Based on the available data extracted from the northern continental slope area of the South China Sea, a 1-D vertical column model was developed. Three cases with different upward methane flux rates and three cases with different mineral compositions, i.e., a total of six cases were designed to investigate the effects of variations in the depth of sulfate methane transition zone (SMTZ) and in the mineral composition on the formation of authigenic minerals. The simulation results indicate that the SMTZ depth influenced by both the upward methane flux rate and the initial composition played an important role in the formation of authigenic minerals. The AOM reaction is intensive at the interface, and the precipitation amount of calcite is large, which is mainly controlled by AOM. When the methane leakage rate is 20 times higher than the base case, aragonite starts to precipitate. During the simulation, oligoclase, k-feldspar, smectite-Na, smectite-Ca, chlorite dissolved. Our study specific to this area as a starting point may provide a quantitative approach for investigating carbonate and pyrite formation in hydrate-bearing sediments accounting for methane oxidation and sulfate reduction. The method presented here and the model built in this study can be used for other sites with similar conditions. In addition, this study may serve as an indication for the potential natural gas hydrate reservoir in depth, and is also significant for marine carbon and sulfur cycle.  相似文献